Abstract

AbstractOn π,π*‐excitation of the epoxyenone (E)‐1 (λ = 254 nm, MeCN), in addition to the previously isolated compounds 2–9, the new products 10–12, derived from the ylide intermediate c were isolated. Further evidence for the ylide c was obtained by the rapid racemization of the optically active epoxyenone (−)‐(E)‐1.

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