Abstract
U.v. irradiation of acidic aqueous solutions of [M(PEt3)3](M = Pt or Pd), or visible irradiation of acidic aqueous solution of [HRh(PPri3)3] produces hydrogen and [M(PEt3)3(H2O)]2+ or [HRh(PPri3)2(H2O)3]2+ respectively.
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