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Abstract
Abstract Photochemical oxidation of benzene, toluene, and ethylbenzene initiated by OH radicals in the presence of NO and NO2 was studied in the air by using a 67 dm3 reaction chamber made of Pyrex glass. OH radicals were produced by photochemical decomposition of nitrous acid, the products being phenol and nitrobenzene for benzene; cresols, benzaldehyde, m- and p-nitrotoluenes, and benzyl nitrate for toluene; ethylphenols, benzaldehyde, acetophenone, and m- and p-nitroethylbenzene for ethylbenzene. The reaction mechanisms are proposed based on the addition of OH radicals to aromatic rings and the hydrogen abstraction of OH radicals from alkyl groups.
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