Abstract

1. Upon irradiation of phosphine hydride complexes of molybdenum and tungsten in benzene or cyclohexane, the products from photochemical dehydrogenation of the complexes are capable of abstracting hydrogen from the solvents, the molybdenum compounds being more reactive than the analogous tungsten complexes. 2. A decrease in the irradiation wavelength increases the efficiency of interaction of MH4L4 with the solvents. 3. Complexes with monodentate ligands are more reactive than complexes containing bidentate ligands.

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