Abstract
Dimerisation par transfert d'electron photosensibilisee, produite par diverses etapes reversibles. Etude sur l'ether de phenyle vinyle. Formation de cis- et trans-diphenoxy-1,2 cyclobutane. L'ouverture de cycle du radical cationique du cis (C + ) se produit dans CH 3 CN a temperature ambiante a constante de vitesse de ∼1,8×10 6 S −1 . La constante de vitesse de transfert d'electron de PVE a C + est ∼1,5×10 8 M −1 •S −1
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