Abstract
Fluorescence from small free radicals of NH, CN, CH and NH 2 has been observed in the 193 nm laser photolysis of methylamine. Mass analysis shows that it is converted to HCN (70%) and acetonitrile (6%) after 3600 shots. It is suggested that the two-photon excitation to a superexcited state participates in the elimination of atomic and/or molecular hydrogen.
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