Abstract
In the quest for efficient catalysts for the CO2 reduction reaction, a doubly N-confused hexaphyrin (DNCH) dinuclear iron complex, [(FeCl)2(DNCH)], was found to be catalytically active in the photochemical CO2 reduction reaction. Electrochemical and spectroelectrochemical measurements revealed that the DNCH ligand functions as a redox center in the CO2 reduction reaction.
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