Abstract
The WO3-Fe3O4/reduced graphene oxide (rGO) composite was synthesized with a hydrothermal method for the photocatalytic removal of diazinon (DZ) in visible light. The influence of catalyst concentration (0.5-1.5g L-1), pH (5-9), and initial pollutant value (5-15mg L-1) on the pesticide degradation was studied. The performance of the WO3-Fe3O4/rGO nanocomposite for DZ degradation under visible light shows 94% degradation of 5mg L-1 DZ for 100min with 1g L-1 nanocomposite, and the degradation kinetic was modeled in pseudo-first order (PFO) and the maximum kobs was 0.0248 min-1. The photocatalytic mechanism and the intermediates of DZ degradation were identified. In addition, the WO3-Fe3O4/rGO catalyst showed reusability after 4 runs. The results of this work illustrate that the WO3-Fe3O4/rGO nanocomposite can be applied for real use owing to its high catalytic performance.
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