Photocatalytic reduction of Cr(VI) to Cr(III) in solution containing ZnO or ZSM-5 zeolite using oxalate as model organic compound in environment

Abstract

Photocatalytic reduction of Cr(VI) to Cr(III) in aqueous solution containing ZnO or ZSM-5 zeolite under ambient condition was studied by using oxalate as model organic compound in the natural environment. ZSM-5 zeolite was characterized by X-ray diffraction (XRD), and point of zero net proton charge (PZNPC) titration. The effect of illumination time, mass content of catalyst (m/V), Cr(VI) initial concentrations, pH, ionic strength, and oxalate concentrations on the photocatalytic reduction of Cr(VI) was determined. The results indicate that the PZNPC of ZSM-5 zeolite is at pH 3.6 ± 0.1. At C[Cr(VI) (initial)] = 2.00 × 10 −4 mol/L, pH 7.5 ± 0.1 and after illumination time of 24 h, the reduction of Cr(VI) were 1.1 × 10 −5 mol/L (no ZSM-5 zeolite, 4.0 × 10 −3 mol/L oxalate) and 1.0 × 10 −5 mol/L (0.4 g/L ZSM-5 zeolite, no oxalate), respectively; whereas the reduction of Cr(VI) achieved 1.0 × 10 −4 mol/L in the presence of 0.4 g/L ZSM-5 zeolite and 4.0 × 10 −3 mol/L oxalate. The removal of Cr(VI) from solution is dependent on pH value. The results are important for the application of zeolites in the treatment of Cr(VI) polluted solution in the natural environment.