Photocatalytic performance of TiO 2 films produced with combination of oxygen-plasma and rapid thermal annealing

Abstract

In this work, a combination of oxygen plasma and rapid thermal annealing was suggested in order to oxidize the surface of titanium into TiO 2. A plasma was formed by employing pure oxygen at 150 W, 300 W, and 400 W under a pressure of 7.5 to 8.5 Pa for 5 to 10 min. The TiO 2 was then subjected to rapid thermal annealing (RTA) at a temperature of 400 to 500 °C for 1 min. From the attained results, an RF power of 300 W for 5 min was observed to be sufficient to produce an optimal photocatalytic TiO 2 film. Optimal conditions were confirmed by additional experiments involving humic acid (HA) degradation of the TiO 2 films. When compared to a traditional TiO 2 film, a TiO 2 film prepared with an oxygen-plasma treatment and RTA system exhibited improved photocatalytic capability for HA photodegradation in an aqueous solution. Therefore, this process proposed in this work can be an excellent alternative to the traditional method for fabricating photocatalytic TiO 2 films.