Photocatalytic oxidation degradability of ammonia–nitrogen and Ni/Co ammonia complexes in ternary precursor wastewater by constructing MoS2/g-C3N4 heterojunction: Performance and mechanism

Abstract

In this study, MoS2/g-C3N4 heterojunction photocatalysts were fabricated in order to treat ammonia–nitrogen wastewater resulting from the production of ternary cathode material precursors used in the manufacture of lithium-ion batteries. The catalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), N2 adsorption–desorption test, UV–Vis diffuse reflectance spectra (UV–Vis DRS), Fourier-transform infrared spectroscopy (FT-IR Nicolet 6700), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). The catalytic efficiency of the catalysts on ammonia–nitrogen and Ni/Co ammonia complexes in the wastewater was investigated by varying MoS2 doping, catalyst dose, adsorption duration, and photocatalysis duration. The results showed 2.0 g/L of MoS2/g-C3N4-1 wt% (photocatalyst with a content of 1 wt% MoS2) has the best photocatalytic efficiency. A degradation efficiency of 87.52 % for ammonia–nitrogen, 98.34 % for nickel and 97.80 % for cobalt was reached after one hour of dark adsorption and four hours of illumination. EDS and XPS analysis revealed that Ni2+/Ni3+ and Co2+/Co3+ were adsorbed from the solution onto the catalyst surface, and that NH4+/NH3 was converted into NO3− and N2.