Photocatalytic nitrogen fixation under an ambient atmosphere using a porous coordination polymer with bridging dinitrogen anions

Abstract

The design of highly electron-active and stable heterogeneous catalysts for the ambient nitrogen reduction reaction is challenging due to the inertness of the N2 molecule. Here, we report the synthesis of a zinc-based coordination polymer that features bridging dinitrogen anionic ligands, {[Zn(L)(N2)0.5(TCNQ-TCNQ)0.5]·(TCNQ)0.5}n (L is tetra(isoquinolin-6-yl)tetrathiafulvalene and TCNQ is tetracyanoquinodimethane), and show that it is an efficient photocatalyst for nitrogen fixation under an ambient atmosphere. It exhibits an ammonia conversion rate of 140 μmol g-1 h-1 and functions well also with unpurified air as the feeding gas. Experimental and theoretical studies show that the active [Zn2+-(N≡N)--Zn2+] sites can promote the formation of NH3 and the detachment of the NH3 formed creates unsaturated [Zn2+···Zn+] intermediates, which in turn can be refilled by external N2 sequestration and fast intermolecular electron migration. The [Zn2+···Zn+] intermediates stabilized by the sandwiched cage-like donor-acceptor-donor framework can sustain continuous catalytic cycles. This work presents an example of a molecular active site embedded within a coordination polymer for nitrogen fixation under mild conditions.