Abstract
An organized collection of visible-light photoredox reactions, mainly based on the use of transition-metal photocatalysts, and leading to the preparation of drugs or pharmacophores is presented. Upon generation of radicals, the key step is the formation of new carbon–carbon, carbon–nitrogen or carbon–oxygen bonds. Examples of late stage transformation of heterocycles, benzylic derivatizations, arylation of 5 or 6-membered (hetero)arenes, rearrangements, Michael-like additions, [3+2] cycloadditions, among others are included.
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