Photocatalytic degradation of reactive red 3 and alachlor over uncalcined Fe–TiO2 synthesized via hydrothermal method

Abstract

AbstractIn this work, Fe3+ was used to modify TiO2 to give improved performance under UV and visible light irradiation. The catalysts were prepared via a hydrothermal method without further calcination. Box–Behnken design was used to investigate the effects of hydrothermal temperature, hydrothermal time, and Fe content (wt%) on the photocatalytic performance of TiO2. Pollutants such as reactive red 3 (RR3) dye and alachlor were examined. The synthesized catalysts have been characterized by many techniques. Photodegradation of RR3 dye was performed under UV light irradiation whereas photodegradation of alachlor was performed under both UV and visible light irradiation. In RR3 photodegradation, the effect hydrothermal settings for temperature and time were found significant and the highest removal percentages were 92 and 94% for 15 and 30 min UV irradiation, respectively. In alachlor photodegradation, the effect of Fe-doping was found significant under both UV and visible light irradiation. The highest remo...