Photocatalytic degradation of bisphenol A by HMS/g-C3N4 composite

Abstract

In this work, hexagonal mesoporous silica/g-C3N4 (HMS/C3N4) was synthesized by heating a mixture of self-prepared HMS and dicyandiamide. The as-prepared materials were characterized by transmission electron microscopy (TEM), X-ray diffractometer (XRD), Fourier transform infrared spectra (FT-IR) and Brunauer–Emmett–Teller analysis (BET). The prepared photocatalysts were applied to decompose bisphenol A (BPA) under UV light illumination. The mass ratios of HMS to melamine were optimized. The results showed that optimal mass ratios HMS to dicyandiamide was 1:1. Even though with the same catalyst dosage (1.0 g/L), the degradation kinetic rate constant of BPA over HMS/C3N4 (0.00526 min−1) was 1.76 times and 1.4 times than those on P25 (0.00298 min−1) and pure C3N4 (0.00383 min−1), while the rate constant of photolysis was only 0.00021 min−1. The enhanced photocatalytic activity of the HMS/C3N4 composite was ascribed to higher specific surface area and less aggregation compared to the pure C3N4. It is feasible and efficient to degrade BPA by HMS/C3N4 composite, which is easier to be separated than pure C3N4 after the pollutant has been removed completely.