Abstract
Asymmetric C sp 3 –C sp 3 cross-electrophile coupling is a powerful tool for C–C bond formation yet still a great challenge in organic chemistry. Recently in Nature , Hyster and co-workers reported a highly stereoselective C sp 3 –C sp 3 cross-coupling of alkyl halides with nitroalkanes by photoexciting the ene-reductase (ERED)-templated charge-transfer (CT) complex. Asymmetric C sp 3 –C sp 3 cross-electrophile coupling is a powerful tool for C–C bond formation yet still a great challenge in organic chemistry. Recently in Nature , Hyster and co-workers reported a highly stereoselective C sp 3 –C sp 3 cross-coupling of alkyl halides with nitroalkanes by photoexciting the ene-reductase (ERED)-templated charge-transfer (CT) complex.
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