Abstract
Abstract The link between the structure of carbons and their performance toward catalytic benzylic oxidation by air is studied. Catalytic activity and selectivity of pristine and oxidized carbons can be enhanced, altered, or suppressed by ambient light. The photocatalytical performance of a carbonaceous material depends on the presence of defects, surface area, porosity, and surface oxidation. Adsorption of the hydroperoxide intermediate on the catalyst's surface is suggested as a key process that links the structure of the carbonaceous material with its catalytic activity. The potential of catalysis by carbon black and photocatalysis by graphite nanofibers for greener organic synthesis has been demonstrated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
