Abstract

A polymer film containing the photo-acid generator, 1,2-naphthoquinone-2-diazido-5-sulfonic acid sodium salt (SNQD), and a fluorescence pH indicator, seminaphthofluorescein (SNAFL-1), has been used as a near-field write-once memory medium. Near-field 455 nm light from a optical fiber tip with a nano-size (∼ 100 nm) aperture produced acids in a small area and the acids were detected as the fluorescence intensity increased with the near-field 488 nm excitation light. The fluorescent spot-size was as small as 160 nm and could be read many times without destruction.

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