Abstract

This note reports the first observation of luminescence in n-type single crystal AlAs grown by vapor-phase epitaxy. Silicon is the dominant donor, and Mg is the dominant acceptor. At 77°K, the emission spectra are dominated by bands at 2.16 and 1.73 eV, while at 7°K, the emission is mostly via a band at ∼ 2.1 eV. It is estimated that the “optical” ionization energy of Si donors in AlAs is ∼ 70 meV.

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