Abstract
Phosphorus-containing dendrimers 1-[G'(1)]-1-[G'(4)] (generation 1 to generation 4) possessing terminal aldehyde groups reacted with a variety of hydrazino compounds. Addition of hydrazine itself to 1-[G'(1)]-1-[G'(4)] afforded the corresponding dendrimers 2-[G(1)]-2-[G(4)] with hydrazono groups at the periphery. Addition of methylhydrazine to 1-[G'(1)], 1-[G'(4)] gave the dendrimers 3-[G(1)], 3-[G(4)]. A Schiff reaction between 1-[G'(1)]-1-[G'(4)] and 1-amino-4-(2-hydroxyethyl)piperazine led to dendrimers 5-[G(1)]-5-[G(4)] possessing up to 48 alcohol chain ends. Treatment of 1-[G'(1)], 1-[G'(3)] with fluorenone hydrazone gave rise to macromolecules 7-[G(1)], 7-[G(3)] while the reaction of 1-[G'(1)], 1-[G'(2)], 1-[G'(4)] with 4-aminobenzo-15-crown-5 afforded the macromolecules 9-[G(1)], 9-[G(2)], 9-[G(4)] in which up to 48 crown ether units are anchored on the surface. Wittig reactions between 1-[G'(1)]-1-[G'(4)] with (acetylmethylene)triphenylphosphorane (10) or (cyanomethylene)triphenylphosphorane (12) allowed the formation of dendrimers 11-[G(1)]-11-[G(4)] or 13-[G(1)], 13-[G(4)] with alpha,beta unsaturated ketones or cinnamonitrile units, respectively, on the surface. Disubstitution of terminal P(S)Cl(2) groups of dendrimers 1-[G(1)]-1-[G(7)] with allylamine, propargylamine, or N-(trimethylsilyl)imidazole easily occurred to give macromolecules 14-[G(1)]-14-[G(7)], 15-[G(1)], 15-[G(4)], 16-[G(1)], 16-[G(4)].
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