Abstract

To understand the cause of the high content of phosphorus in the North Chaohu Lake Catchment of China, the distribution of the total phosphorus in groundwater and the dissolution of rock phosphorus near Chaohu Lake were investigated, and a few interesting findings have been revealed. Firstly, four main processes affecting the groundwater quality in North Chaohu Lake Catchment were identified with the results of factor analysis, including anthropogenic activities and the dissolution of carbonate rocks, phosphorus, and fluorine-bearing minerals. Secondly, the dissolution of rock phosphorus can be well described using the one-dimensional diffusion equation, with a semi-infinite boundary condition, and the Langmuir kinetic equation. A relatively low ambient temperature (less than 25 °C) was probably responsible for the small diffusion coefficient compared to that of the previous studies. Thirdly, the high-potential maximum dissolution of rock phosphorus (Cmax) indicated that the dissolution of rock phosphorus could pose a risk to the ambient water body, and Cmax was found to be independent of the total rock phosphorus content.

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