Phosphorus Sorption in Hydromorphic Soils Overlying Alluvium and Coastal Plain Sand Parent Materials in Delta State, Nigeria

Abstract

ABSTRACTHighly weathered soils of the tropics are known to have great affinity for phosphate sorption with reportedly high values for affinity constant, k. This study evaluated soil samples from profiles dug at Agbor, Kwale, and Otegbo which overly alluvium and coastal plain sand parent materials for their capacities to sorb phosphorus (P). The samples were equilibrated in 30 ml of 0.01 M calcium chloride (CaCl2) containing various amounts of P as monopotassium phosphate (KH2PO4) to give 0, 25, 50, 100, 150, 200, 400, 800, and 1000 μg/L P for 6 days at a temperature of 25 ± 2°C. The rate of P adsorption increased with increased concentrations of P and was generally low in the soils. Affinity constant k was also low and did not compare with values earlier obtained for well-drained soils. P adsorption capacity decreased in the order: Agbor > Otegbo > Kwale. Percent phosphorus sorbed was highest at Agbor with values of 11.33%, 10.8%, and 10.12% for 50, 100, and 150 mg/kg P added, respectively. The adsorption maxima (b) of the soils was significantly correlated with the soils organic carbon with r = 0.817, p < 0.05; r = 0.883, p < 0.05, and r = 0.886, p < 0.05 for Agbor, Kwale, and Otegbo soils, respectively. Proper management of the soils organic matter content coupled with the addition of rock phosphate is recommended for P improvement in these soils for sustained cultivation of crops such as Raphia hookeri that are adapted to hydromorphic environment.