Phosphorus-modified mesoporous niobium pentoxide catalyst for fast pyrolysis of cellulose to selective production of levoglucosenone

Abstract

Catalytic fast pyrolysis of biomass/cellulose is a promising way for the production of levoglucosenone (LGO) and other value-added anhydrosugars. Herein, ammonium dihydrogen phosphate (NH4H2PO4) modified mesoporous niobium pentoxide (P-Nb2O5) was first applied to selectively produce LGO. The catalyst had a stable amorphous mesoporous structure with abundant activity species (Nb-O-Nb, Nb-O-P, P-OH, and PO43-), which affected the dehydration and depolymerization reactions of cellulose to alter the competing relationship between levoglucosan (LG) and LGO. Micro-scale pyrolysis experiments demonstrated that the yield of LGO reached 19.6 wt% under the optimized condition (P loading of 50 wt%, pyrolysis temperature of 400 °C, and catalyst-to-cellulose mass ratio of 7). In lab-scale experiments, the highest yield of LGO attained 16.5 wt%, and the catalytic activity could maintain over 80% after five recycles. Overall, the P-Nb2O5 has been proven to be a promising catalyst to produce LGO from cellulose.