Abstract
AbstractSeveral phosphorus derivatives of methyl 2‐(chloromethyl)acrylate, including three phosphonium salts and one phosphonate ester have been prepared. A brief study was made of their polymerization characteristics under free‐radical conditions. Several factors were noted which prevented the synthesis of methyl 2‐[(diethoxyphosphinyl)‐methyl]acrylate in high yields in initial experiments. Homopolymerization of these phosphorus derivatives does not take place readily in the presence of free‐radical initiators.
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