Abstract
The reaction of Ph 2PH with [Ru 3(CO) 10( μ-dppm)] ( 1) at 98°C gave [Ru 3( μ-CO)(CO) 6( μ-PPh 2) 2( μ 3-CH 2PPh)] ( 7) in 20% yield. Compound 7 was characterized by elemental analysis, 1H and 31P{ 1H} NMR and mass spectroscopic data and also by a single crystal structure determination. The compound is shown to consist of a triruthenium cluster with an unusual example of a triply bridging CH 2PPh ligand and two doubly bridging PPh 2 ligands.
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