Abstract

Based on the assumption that silicate application can raise soil P availability for crops, the aim of this research was to compare the effect of silicate application on soil P desorption with that of liming, in evaluations based on two extractors and plant growth. The experiment was carried out in randomized blocks with four replications, in a 3 × 3 × 5 factorial design, in which three soil types, three P rates, and four soil acidity correctives were evaluated in 180 experimental plots. Trials were performed in a greenhouse using corn plants in 20-dm³ pots. Three P rates (0, 50 and 150 mg dm-3) were applied in the form of powder triple superphosphate and the soil was incubated for 90 days. After this period, soil samples were collected for routine chemical analysis and P content determination by the extraction methods resin, Mehlich-1 and remaining P. Based on the results, acidity correctives were applied at rates calculated for base saturation increased to 70 %, with subsequent incubation for 60 more days, when P content was determined again. The acidity correctives consisted of: dolomitic lime, steelmaking slag, ladle furnace slag, and wollastonite. Therefore, our results showed that slags raised the soil P content more than lime, suggesting a positive correlation between P and Si in soil. Silicon did not affect the extractor choice since both Mehlich-1 and resin had the same behavior regarding extracted P when silicon was applied to the soil. For all evaluated plant parameters, there was significant interaction between P rates and correctives; highest values were obtained with silicate.

Highlights

  • The reaction of phosphate ion adsorption to soil colloids is directly related to the reaction conditions of soil, since with a rise of pH the solubility of iron and aluminum phosphates is increased with reduction of phosphate anion adsorption to the soil solid phase

  • The lime and ladle furnace slag had a similar behavior, which can be explained by the similarity in reactivity and RPTN of these products

  • The same was not true for steelmaking slag, which had lower pH values than the other correctives; this fact can be explained by the larger grain size and, the longer time required for reaction (Table 3)

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Summary

Introduction

The reaction of phosphate ion adsorption to soil colloids is directly related to the reaction conditions of soil, since with a rise of pH the solubility of iron and aluminum phosphates is increased with reduction of phosphate anion adsorption to the soil solid phase. The extractor Mehlich-1, widely used in routine laboratory analyses across the country, may overestimate available P contents in soils treated with rock phosphate, or in situations where inorganic CaP contents are higher due to low weathering (Novelino et al, 1985). This extractor may underestimate available P in soils with high clay content, due to the resulting extractor wear (Novais & Kamprath, 1979, Muniz et al, 1987). The resin method is questionable due to the likely underestimation of labile

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