Abstract

Monolithic phosphor-free two-color gallium nitride (GaN)-based white light emitting diodes (LED) have the potential to replace current phosphor-based GaN white LEDs due to their low cost and long life cycle. Unfortunately, the growth of high indium content indium gallium nitride (InGaN)/GaN quantum dot and reported LED’s color rendering index (CRI) are still problematic. Here, we use flip-chip technology to fabricate an upside down monolithic two-color phosphor-free LED with four grown layers of high indium quantum dots on top of the three grown layers of lower indium quantum wells separated by a GaN tunneling barrier layer. The photoluminescence (PL) and electroluminescence (EL) spectra of this white LED reveal a broad spectrum ranging from 475 to 675 nm which is close to an ideal white-light source. The corresponding color temperature and color rendering index (CRI) of the fabricated white LED, operated at 350, 500, and 750 mA, are comparable to that of the conventional phosphor-based LEDs. Insights of the epitaxial structure and the transport mechanism were revealed through the TEM and temperature dependent PL and EL measurements. Our results show true potential in the Epi-ready GaN white LEDs for future solid state lighting applications.

Highlights

  • In nitride based semiconductors, the indium gallium nitride (InGaN) compound semiconductor has been used to fabricate light emitting diodes (LEDs) and laser diodes ranging from ultra violet to visible light by modulating the composition of indium-gallium ratio to vary the correspondent energy gap between 0.7 eV and 3.4 eV [1,2,3,4,5]

  • This technology has been widely adopted in commercial white LEDs, extra costs have resulted from the high reaction temperature and the high pressure required for synthesizing phosphors, which is a critical drawback

  • The scanning transmission electron microscope (STEM) images revealed four layers of the green-yellow quantum dots (QDs) structure on top of the three layers of the blue quantum well (QW) structure, which are shown in Figure 2e,f with different magnifications

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Summary

Introduction

The indium gallium nitride (InGaN) compound semiconductor has been used to fabricate light emitting diodes (LEDs) and laser diodes ranging from ultra violet to visible light by modulating the composition of indium-gallium ratio to vary the correspondent energy gap between 0.7 eV and 3.4 eV [1,2,3,4,5]. Developed the first white light emitting diodes (LEDs) using the GaN based blue LEDs. Materials 2017, 10, 432; doi:10.3390/ma10040432 www.mdpi.com/journal/materials. Materials 2017, 10, 432 and yellow yttrium aluminum garnet (YAG) phosphor. Most of the mature white LEDs are still based on the blue InGaN chips coupled with the yellow-emitting YAG phosphor. This technology has been widely adopted in commercial white LEDs, extra costs have resulted from the high reaction temperature (over 1800 ◦ C) and the high pressure required for synthesizing phosphors, which is a critical drawback. Many research groups aimed to develop a gallium nitride (GaN)-based phosphor-free white LED utilizing two-color

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