Abstract
Main observation and conclusionA catalytic two‐component three‐centered (2C3C) Ugi‐type reaction was developed for the synthesis of L‐1‐deoxynojirimycin (DNJ) isomers using a chiron approach. This new and quite mild catalytic system, comprised of phenylphosphinic acid/NaI, was used to synthesize both the L‐allo‐DNJ and L‐altro‐DNJ in high yield.
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