Phosphate removal from aqueous solution using calcium-rich biochar prepared by the pyrolysis of crab shells.

Abstract

Phosphorus is one of the main pollutants that cause water pollution, and phosphorus is a one-way cycle in the environment, and phosphorus resources will face exhaustion in the next 100years. Therefore, the recovery and reuse of phosphorus resources have become very important. This article presents a study concerning the removal of phosphate from an aqueous solution by using a calcium-rich biochar prepared by pyrolysis of crab shells. The experimental results show that the optimal pyrolysis temperature of crab shells is 500℃, named CSB500, which is more conducive to the adsorption of phosphate. The process of phosphate adsorption conforms to the quasi-second-order kinetics and Freundlich model. On the other hand, the Langmuir isotherm model shows that when the reaction conditions are 25℃, 30℃, and 35℃, the maximum adsorption capacity of CSB500 for phosphate is 164.32mg/g, 170.47mg/g, and 209.35mg/g, respectively. The characterization results show that the overall structure of CSB500 is good, the specific surface area is large, and the main component is calcium carbonate. The potential mechanisms of action in the process of phosphate adsorption may be electrostatic attraction, surface chemical precipitation, ligand exchange, and complexation.