Phosphate and feldspar mineralogy of equilibrated L chondrites: The record of metasomatism during metamorphism in ordinary chondrite parent bodies

Abstract

AbstractIn ordinary chondrites (OCs), phosphates and feldspar are secondary minerals known to be the products of parent‐body metamorphism. Both minerals provide evidence that metasomatic fluids played a role during metamorphism. We studied the petrology and chemistry of phosphates and feldspar in petrologic type 4–6 L chondrites, to examine the role of metasomatic fluids, and to compare metamorphic conditions across all three OC groups. Apatite in L chondrites is Cl‐rich, similar to H chondrites, whereas apatite in LL chondrites has lower Cl/F ratios. Merrillite has similar compositions among the three chondrite groups. Feldspar in L chondrites shows a similar equilibration trend to LL chondrites, from a wide range of plagioclase compositions in petrologic type 4 to a homogeneous albitic composition in type 6. This contrasts with H chondrites which have homogeneous albitic plagioclase in petrologic types 4–6. Alkali‐ and halogen‐rich and likely hydrous metasomatic fluids acted during prograde metamorphism on OC parent bodies, resulting in albitization reactions and development of phosphate minerals. Fluid compositions transitioned to a more anhydrous, Cl‐rich composition after the asteroid began to cool. Differences in secondary minerals between H and L, LL chondrites can be explained by differences in fluid abundance, duration, or timing of fluid release. Phosphate minerals in the regolith breccia, Kendleton, show lithology‐dependent apatite compositions. Bulk Cl/F ratios for OCs inferred from apatite compositions are higher than measured bulk chondrite values, suggesting that bulk F abundances are overestimated and that bulk Cl/F ratios in OCs are similar to CI.