Abstract
In order to interpret the photoluminescence spectra of spherical nanocrystals with zincblende structure, the intensities of phonon satellites are analyzed taking into account both the internal non-adiabaticity of the exciton-phonon system (the proper Jahn-Teller effect) and the external non-adiabaticity (the pseudo-Jahn-Teller effect). The effects of non-adiabaticity are shown to lead to a significant enhancement of phonon-assisted transition probabilities and to a more complicated dependence of these probabilities on the number of emitted or absorbed phonons in comparison with the results of adiabatic theory. The calculated relative intensities of the phonon satellites compare well with the experimental data on the photoluminescence of the CdSe spherical nanocrystals.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
