Abstract

AbstractHere, we review the progress and most recent advances in phonon-polaritonics, an emerging and growing field that has brought about a range of powerful possibilities for mid- to far-infrared (IR) light. These extraordinary capabilities are enabled by the resonant coupling between the impinging light and the vibrations of the material lattice, known as phonon-polaritons (PhPs). These PhPs yield a characteristic optical response in certain materials, occurring within an IR spectral window known as the reststrahlen band. In particular, these materials transition in the reststrahlen band from a high-refractive-index behavior, to a near-perfect metal behavior, to a plasmonic behavior – typical of metals at optical frequencies. When anisotropic they may also possess unconventional photonic constitutive properties thought of as possible only with metamaterials. The recent surge in two-dimensional (2D) material research has also enabled PhP responses with atomically-thin materials. Such vast and extraordinary photonic responses can be utilized for a plethora of unusual effects for IR light. Examples include sub-diffraction surface wave guiding, artificial magnetism, exotic photonic dispersions, thermal emission enhancement, perfect absorption and enhanced near-field heat transfer. Finally, we discuss the tremendous potential impact of these IR functionalities for the advancement of IR sources and sensors, as well as for thermal management and THz-diagnostic imaging.

Highlights

  • The fast pace in progress of visible/near-infrared (IR) plasmonic optics [1, 2] has not been mirrored in the IR part of the electromagnetic (EM) spectrum

  • In order to provide a context for what capabilities and directions phonon-polariton platforms bring about in IR photonics we briefly review widelyresearched metallic platforms for IR light and discuss their possibilities and limitations

  • A more moderate fanis of about 20% is expected for transition metal dichalcogenides (TMDs), much smaller than that of hexagonal boron nitride (hBN), which has an fanis of about 50%, but still much larger than that of the traditional semiconductors of Table 3, which have an fanis of about 10% or less

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Summary

Introduction

The fast pace in progress of visible/near-infrared (IR) plasmonic optics [1, 2] has not been mirrored in the IR part of the electromagnetic (EM) spectrum.

Metallic platforms for IR light: possibilities and limitations
W hat are PhPs?
M ω2R ε0
The PhP gap and the reststrahlen band
Widely-used and emergent PhP materials
Isotropic semiconductors
Anisotropic semiconductors
O ther anisotropic PhP material hBN
PhPs in the “flatland”: 2D and quasi-2D PhP materials
P hotonic responses in isotropic PhP material
IR plasmonic-like responses
IR ENZ responses
Photonic responses in anisotropic PhP material
Uniaxial PhP material
Biaxial PhP material
The essential building blocks of IR phonon-polaritonics
C onfined PhP modes at planar interfaces and ultrathin films
Particle PhPs
Ordinary particle PhPs
New physics with particle PhPs
Patterned PhP materials: metamaterials and mesophotonic platforms
Hyperbolic PhP metamaterials
Highly tailorable anisotropic PhP metamaterials
M agnetic PhP metamaterials
PhP-based mesophotonic systems
Particle-PhP arrays: metasurfaces
Perforated PhP-material arrays
P hotonic-crystal-based PhP systems
D oping-tunable PhP permittivity in semiconductors: the LOPC effect
E lectric-field tunable PhP responses: the case of ferroelectrics
Turning PhP photonic responses on and off by phase transitions
Hybrid platforms with PhPs
Findings
10 C onclusions and outlook
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