Phenylgermanium and phenyltin derivatives of rhenium carbonyl

Abstract

1. The reactions of organogermanium halides Ph4−nGeXn with the sodium salt of rhenium pentacarbonyl were used to produce Ph3GeRe(CO)5 and Ph2Ge[Re(CO)5]2. 2. The action of halogens (Br2) or hydrohalic acids (HCl) was used to produce Br3GeRe(CO)5 and\(\begin{gathered} Ph_2 GeRe\left( {CO} \right)_5 \hfill \\ | \hfill \\ Cl \hfill \\ \end{gathered} \). 3. In the reaction of PPh3, AsPh3, SbPh3with Ph3GeRe(CO)5 and Ph3SnRe(CO)5, the corresponding derivatives with the general formula Ph3M-Re(CO)4L, were obtained, where M=Ge, Sn; L=PPh3; AsPh3; SbPh3.