Abstract
The distribution of phenyldibenzofurans (PhDBFs) and methyldibenzofurans (MDBFs) and their potential implications in petroleum organic geochemistry have been investigated for sediment extracts and crude oils derived from lacustrine shale, marine shale, marine carbonate, and terrestrial (fluvial/deltaic/fresh water) mudstone. PhDBF isomers in a set of lacustrine shales from the Liaohe Basin (East China) are identified in the m/z 244 mass chromatograms of the aromatic fraction by coinjection of internal synthetic standards on a high resolution capillary column (HP-5MS). The results show that the relative abundance of 4-PhDBF/2-PhDBF and 4-PhDBF/(2-PhDBF+3-PhDBF) increase gradually with increasing burial depth and maturity (R0 ≥ 0.6%), and have a good correlation with vitrinite reflectance in lacustrine shales from wells S202 and SG1 in the Liaohe Basin. These two ratios, defined as phenyldibenzofuran ratio-1 and -2 (PhFR-1 and PhFR-2), may be potential maturity indicators for mature sediments in this study....
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