Abstract

Styrene oligomers can be separted isocratically on phenyl-bonded phases using tetrahydrofura—water, tetrahydrofuran—hexane and acetonitrile—water eluents. The retention of the styrene oligomers follows Snyder' capacity factor formulation. An equation which incorporated the Martin and the Snyder relations between log k' and degree of polymerization and solvent composition can be used to estimate the isocratic retention of styrene oligomers.

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