Abstract
The asymmetric unit of the title compound, C12H8N2·C10H10N2·2H2O, contains one half-molecule of phenazine, one half-molecule of naphthalene-1,5-diamine and one water molecule. The phenazine and naphthalene-1,5-diamine molecules are located on inversion centers. The water molecules serve as bridges between the naphthalene-1,5-diamine molecules and also between the naphthalene-1,5-diamine and phenazine molecules. The naphthalene-1,5-diamine and water molecules are connected via N—H⋯O and O—H⋯N hydrogen bonds, forming a T4(2) motif. They are arranged into a two-dimensional polymeric structure parallel to (10) in which the water molecule is a single donor and a double acceptor, whereas the amino group is a double donor and a single acceptor in the hydrogen bonding. These two-dimensional assemblies alternate with the layers of phenazine molecules arranged into a herringbone motif. Each phenazine molecule is hydrogen bonded to two water molecules and thus a three-dimensional framework of hydrogen-bonded molecules is generated.
Highlights
The asymmetric unit of the title compound, C12H8N2C10H10N22H2O, contains one half-molecule of phenazine, one half-molecule of naphthalene-1,5-diamine and one water molecule
The phenazine and naphthalene-1,5-diamine molecules are located on inversion centers
The water molecules serve as bridges between the naphthalene-1,5-diamine molecules and between the naphthalene-1,5-diamine and phenazine molecules
Summary
The naphthalene-1,5-diamine and water molecules are connected via N—H O and O—H N hydrogen bonds, forming a T4(2) motif. They are arranged into a two-dimensional polymeric structure parallel to (101) in which the water molecule is a single donor and a double acceptor, whereas the amino group is a double donor and a single acceptor in the hydrogen bonding. These two-dimensional assemblies alternate with the layers of phenazine molecules arranged into a herringbone motif. Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RZ2392)
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