Abstract

Model of electronic subsystem of (BEDT-TTF)2X family is studied theoretically within Green function equation of motion approach. The configurational representation of the model Hamiltonian which allows analytical calculation of the energy spectrum is developed. Effective Hamiltonian of the model takes into account the strong intra-site Coulomb, intersite exchange interaction of electrons and correlated hopping of electrons both within the conducting plane and in transversal direction. With rise of intraatomic Coulomb repulsion in the energy spectrum a gap opens and the transition to antiferromagnetic state is realized. At the external pressure and decreasing temperature the transition from insulator to metallic phase occurs. The experimental phase diagrams for quasi-twodimensional organic conductors with strong electron correlations and correlated hopping are discussed.

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