Abstract

Abstract Dielectric Constant (ϵ′), thermoelectric power (S) and electrical conductivity (σ) were determined for a superionic material 60 AgI-20 AgSO-20 AgPO3 over a temperature range of 30°C-210C, usingan indigenously fabricated equipment. It was observed that the dielectric constant kept on decreasing and reached a value of almost zero around 148°C and then started shooting up as the temperature of the material was increased. The reason for this interesting behaviour was been analysed in terms of phase-transition. The values of thermoelectric power and electrical conductivity increased with the rise of temperature throughout the range of temperatures studied and no abnormality in these values was observed around 148°C.

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