Abstract

AbstractIt was found that 1,16‐hexadecanediol exhibited a solid‐solid phase transition. X‐ray diffraction experiments and dielectric constant measurements were carried out in order to investigate the structure of the high‐temperature phase. A model of molecular arrangement in the high‐temperature phase was presented. The high‐dielectric constant values were observed in the high‐temperature phase. It is considered that the high‐temperature phase of 1,16‐hexadecanediol is a rotator phase in analogy with n‐higher alcohols.

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