Abstract
The ferroelectric phase transition in triglycine sulfate ((NH2CH2COOH)3·H2SO4, TGS)) crystals, occurring at TC of 322K, was studied using 1H and 13C CP/MAS NMR. From the spin–lattice relaxation time in the rotating frame, T1ρ, of 1H and 13C, we found that the slopes of the T1ρ versus temperature curve changed near TC. In addition, the change of intensities for the protons and carbons NMR signals in the ferroelectric and the paraelectric phases led to the noticeable changes in the environments of proton and carbon in the carboxyl groups. The carboxyl ordering was the dominant factor driving the phase transition. Our study of the 1H and 13C spectra showed that the ferroelectric phase transition of TGS is of the order–disorder type due to ordering of the carboxyl groups.
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