Abstract
The nature of phase transformations and phase equilibria in the Ti- V - N system with about 20 at.-%V and 11 -15 at.-%N has been studied at 1200°C. The results obtained for the titanium rich corner of the Ti - V- N phase diagram provide new information on phase coexistence and the composition of particular phases in this system. Thermodynamic calculations, based on the use of thermodynamic parameters from the three binary subsystems, together with newly assessed thermodynamic parameters published previously, were carried out. Reasonable agreement was obtained between the experiment and the calculations.
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