Phase Transformation Behavior of a Two‐Dimensional Zeolite

Abstract

AbstractUnderstanding the molecular‐level mechanisms of phase transformation in solids is of fundamental interest for functional materials such as zeolites. Two‐dimensional (2D) zeolites, when used as shape‐selective catalysts, can offer improved access to the catalytically active sites and a shortened diffusion length in comparison with their 3D analogues. However, few materials are known to maintain both their intralayer microporosity and structure during calcination for organic structure‐directing agent (SDA) removal. Herein we report that PST‐9, a new 2D zeolite which has been synthesized via the multiple inorganic cation approach and fulfills the requirements for true layered zeolites, can be transformed into the small‐pore zeolite EU‐12 under its crystallization conditions through the single‐layer folding process, but not through the traditional dissolution/recrystallization route. We also show that zeolite crystal growth pathway can differ according to the type of organic SDAs employed.