Abstract
A-site cation substitution with Ba2+ or Ca2+ ions was made for the ordered complex perovskite Sr(Y0.5Ta0.5)O3 to correlate the structure evolution and the change in the temperature coefficient of relative permittivity (TCer) with the cation substitution. The crystal symmetry of the solid solutions at room temperature changed as monoclinic → rhombohedral → cubic with the corresponding A-site cation species of Ca2+ → Sr2+ → Ba2+. On heating, the rhombohedral phase of Sr(Y0.5Ta0.5)O3 was firstly transformed to the cubic phase with a lower symmetry (F43m or F432) at 1000°C and further to the ideal cubic phase (Fm3m) at 1300°C. The similar phase transformation behavior at elevated temperatures was observed for each of the Ba2+-substituted perovskites, both the phase transformation temperatures being lowered with increasing Ba2+ content. TCer of the ordered perovskites monotonously increased over the temperature range where the phase transformation regions from monoclinic to rhombohedral or from rhombohedral to cubic (F43m or F432) occurred. On the other hand, a subtle symmetry change in the cubic phase from F43m (F432) to Fm3m caused a remarkable change in the TCer from positive to negative at the transformation temperature. These results suggested that the positive TCer is essentially correlated to the relaxation of the tilting of the BO6 octahedra in the perovskite structure on heating.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.