Abstract
Reductions of metal carbonyl halides and some metal carbonyls by quaternary ammonium borohydrides in phase transfer catalyzed reactions are described. The method provides an efficient synthetic route to metal carbonyl anions from BrMn(CO) 5, C 5H 5Mo(CO) 3Cl, Fe 3(CO) 12 and Co 2(CO) 8 and yields the corresponding hydrides from BrMn(CO) 4Ph 3 and C 5H 5Ru(CO) 2Br.
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