Phase morphology and tribological properties of PI/UHMWPE blend composites

Abstract

Polyimide/ultrahigh molecular weight polyethylene (PI/UHMWPE) blends with different mass ratio were produced. A ratio-image method was adopted by plotting the ratio of Raman peak intensity of a typical band of PI with that of UHMWPE as a function of position, Raman Mapping images with a relatively high accuracy and enhanced visualization were obtained. Two-phase distribution morphologies of the blends were studied using Raman Mapping. Effects of blend phase morphology and phase distribution on the tribological properties of blend composites were investigated. The results indicated that both the phase structures and their distribution are obviously different for the PI/UHMWPE blends with different mass ratios, which significantly influence the tribological properties of the blends. PI phase disperses in an island form in the UHMWPE matrix phase when the mass ratio of PI/UHMWPE is relatively small (10/90). The scattered PI dispersed phase effectively reduces the friction coefficient of the blend and improves the wear resistance. For the PI/UHMWPE blend composite with the mass ratio of 30/70, layered PI phase forms and distributes in the UHMWPE matrix phase, improving bearing capacity and wear resistance of the blends. Large continuous area structure and phase separation occurs in the blend when the mass ratio of PI/UHMWPE increases to 50/50, resulting in a significant reduction in the wear resistance of the blend composite.