Phase inverted hydrophobic polyethersulfone/iron oxide-oleylamine ultrafiltration membranes for efficient water-in-oil emulsion separation

Abstract

Exploration and transportation of oil offshore can result in oil spills that cause a wide range of adverse environmental consequences and destroy aquatic life. Membrane technology outperformed the conventional procedures for oil emulsion separation due to its improved performance, reduced cost, removal capacity, and greater eco-friendly. In this study, a hydrophobic iron oxide-oleylamine (Fe-Ol) nanohybrid was synthesized and incorporated into polyethersulfone (PES) to prepare novel PES/Fe-Ol hydrophobic ultrafiltration (UF) mixed matrix membranes (MMMs). Several characterization techniques were performed to characterize the synthesized nanohybrid and fabricated membranes, including scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), contact angle, and zeta potential. The membranes' performance was assessed using a surfactant-stabilized (SS) water-in-hexane emulsion as a feed and a dead-end vacuum filtration setup. The incorporation of the nanohybrid enhanced the hydrophobicity, porosity, and thermal stability of the composite membranes. At 1.5 wt% Fe-Ol nanohybrid, the modified PES/Fe-Ol MMM membranes reported high water rejection efficiency of 97.4% and 1020.4 LMH filtrate flux. The re-usability and antifouling properties of the membrane were examined over five filtration cycles, demonstrating its great potential for use in water-in-oil separation.