Phase fractionation and oil mixing as contributors to complex petroleum phase in deep strata: A case study from LG7 block in the Tarim Basin, China

Abstract

Integrated geochemical analysis was conducted on oil and gas samples from the LG7 block, Tarim Basin, China, to investigate the causal mechanisms for the complex petroleum phase. Consistency in biomarker derived parameters suggest that heavy oil, black oil, and condensate, though vary in physical properties and phase state, share a genetic affinity and are all mature oil generated at peak oil window. However, mass loss and double-peaks pattern in n-paraffins of black oil and heavy oil, and much higher maturity of gas and some oil fractions (diamondoids) jointly suggest the oil samples in the study site have suffered secondary alteration process including phase fractionation and mixing. In combination with tectonic evolution analysis, the study site experienced severe uplift after primary oil accumulation and thus formed biodegraded heavy oil in local highs. Since Neogene, the introduction of oil-cracking gas from deeper strata charged early oil accumulations and caused phase fractionation, during which primary oil was fractionated into vaporized light oil and heavy oil residue. Vaporized light oil continued to migrate towards higher positions and were readily to either mix with other oil residue and heavy oil, or to be trapped to form secondary condensate in favorable reservoirs. Thus, the complex disordered distribution of heavy oil, black oil, and condensate is observed within a relatively small area. Our reconstruction of the petroleum accumulation and alteration process speculates future exploration endeavors to potential oil-cracking gas/condensate accumulations in the study area.