Abstract
Using X‐ray diffraction analysis and scanning electron microscopy it was revealed that in an atmosphere of flowing oxygen in the temperature range 700°–800°C, three new compounds are formed in the Bi2O3–TiO2–TeO2 pseudoternary system. These compounds are Bi2Ti3TeO12, Bi2TiTeO8, and Bi6Ti5TeO22, and all the compounds include Te6+. All three crystal structures were solved and refined using X‐ray powder diffraction data. Based on the results of the phase formation, a solid‐state compatibility diagram is proposed.
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