Phase formation and carbonation impact on the strength of alkali-activated demolition waste with calcium compounds

Abstract

The present study evaluates the impact of calcium compounds on the reaction kinetics of alkali-activated construction demolition waste. Two materials, concrete and brick demolition waste, were milled to powders and supplemented with either carbonated cement stone or freshly ground cement stone. The mixed solids were further subjected to alkaline activation using a sodium silicate solution. X-ray diffraction, isothermal conduction calorimetry, thermogravimetric analysis, scanning electron microscopy and compressive strength tests were employed to understand the interaction of the reactants. The results indicate that cubes prepared from freshly ground cement stone exhibited higher compressive strength of around 18 MPa than those from carbonated cement stone with a maximum of 7 MPa. This superior strength was approved by subsequent analysis methods. A more significant reaction was observed in the material containing freshly ground cement stone, resulting in increased strength within the system. The presence of portlandite in freshly ground cement stone facilitated the initial formation of calcium silicate hydrate phases.