Abstract
Vapor−liquid equilibria are reported for the following five systems: phenol + styrene; ethyl mercaptan + n-butane; tert-butyl mercaptan + propane; dimethyl ether + propane; trifluoroacetic acid + hydrogen chloride. The system pressure and temperature were measured at several charge compositions along two isotherms for each system. Equilibrium vapor- and liquid-phase compositions were derived from the PTx data using the Soave equation of state to represent the vapor phase and the Wilson or NRTL activity coefficient model to represent the liquid phase. Liquid−liquid equilibrium studies were performed on the dimethyl carbonate + water system at two temperatures by analyzing samples taken from each liquid phase. The solubility of hydrogen in α-methyl benzyl alcohol was measured at three pressures at each of three temperatures.
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